Human exposure to BTEX emitted from a typical e-waste recycling industrial park: External and internal exposure levels, sources, and probabilistic risk implications.

Benzene, toluene, ethylbenzene, and xylene (BTEX) can be released during extensive activities associated with the disposal of electronic waste (e-waste), which might pose deleterious health effects on workers. In this study, pollution profiles of BTEX in air and their urinary excretive profiles in occupational workers were investigated in a typical e-waste recycling industrial park. The results showed that the workers in the park were generally exposed to high levels of BTEX. The median levels of urinary metabolites were approximately 6-orders of magnitude higher than those of unmetabolized BTEX, indicating that pollutants efficiently metabolize at those occupational levels. The analytes presented differential profiles in external and internal exposure. Among the metabolites, significant correlation (p < 0.05) was observed between N-acetyl-S-benzyl-L-cysteine (S-BMA) concentration and atmospheric individual BTEX derived from the e-waste recycling area, suggesting that S-BMA is a potential marker for BTEX exposure to e-waste occupational workers. Notably, 95.2 % of all the workers showed a cumulative carcinogenic risk induced by BTEX exposure via inhalation, with 99.9 % of the carcinogenic risk distribution based on concentration of benzene metabolite (N-acetyl-S-(phenyl)-L-cysteine) exceeding 1.0E-6. This study holds potential in providing valuable inferences for the development of remediation strategies focusing on BTEX exposure reduction to protect workers' health at e-waste recycling industries.

Volatile organic compounds in an e-waste dismantling region: From spatial-seasonal variation to human health impact.

The dismantling of electrical and electronic waste (e-waste) can release various Volatile organic compounds (VOCs), impacting the surrounding ambient environment. We investigated the spatio-temporal characteristics and health risks of the ambient VOCs emitted in a typical e-waste dismantling region by conducting multi-site sampling campaigns in four seasons. The pollution of benzene, toluene, ethylbenzene, and xylenes (BTEX) in the e-waste dismantling park has relation to e-waste dismantling by seasonal trend analysis. The highest concentrations of most VOCs occurred in winter and autumn, while the lowest levels were observed in summer and spring. The spatial distribution map revealed the e-waste dismantling park to be a hotspot of BTEX, 1,2-dichloropropane (1,2-DCP), and 1,2-dichloroethane (1,2-DCA), while two major residential areas were also the hotspots of BTEX. The e-waste emission source contributed 20.14% to the total VOCs in the e-waste dismantling park, while it was absent in the major residential and rural areas. The cancer risk assessment showed that six VOCs exceeded 1.0 × 10-6 in the e-waste dismantling park, while only three or four compounds exceeded this risk in other areas. The noncancer risks of all compounds were below the safety threshold. This study supplements the existing knowledge on VOC pollution from e-waste dismantling and expands the research scope of chemical pollution caused by e-waste.